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Expanded Porphyrins and Self-assembled Supramolecules including Polypyrroles

등록일
2005년 2월 17일 15시 59분 57초
접수번호
1002
발표코드
토26F6구 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
토 11시 : 40분
발표형식
구두발표
발표분야
재료화학
저자 및
공동저자
신지영
University of British Columbia,
Pyrrole-contaning systems have emerged as many divers area because of the interests in the chemistry of the porphyrin related macrocycles and the self-assemblies. In recently, we reported correlating papers with the series of meso-aryl-substituted expanded porphyrins. In the first part of the presentation, the chemistries of the series of expanded porphyrins will be introduced. Diyrromethenes exhibit rotations of the pyrrolyl groups around the central methine linkage, and three different configurations are expected. With this free rotational property, polypyrrole derivatives have been used as building blocks for self-assemblies. In the second part of the presentation, these three different configurations will be presented comparably according to spectral data of each self-assembly.

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