abs

학술발표회초록보기

초록문의 abstract@kcsnet.or.kr

결제문의 member@kcsnet.or.kr

현재 가능한 작업은 아래와 같습니다.
  • 03월 07일 19시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제107회 대한화학회 학술발표회, 총회 및 기기전시회 안내 A Ru(III) Complex with a Tripodal Pyrazolyl Tetraamine Ligand : Structure, Spectroscopic Properties,and Peroxidase-like Reactivity

등록일
2011년 2월 16일 11시 16분 38초
접수번호
0448
발표코드
Ⅲ-INOR.P-30 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
금 <발표Ⅲ>
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
조장훈, 김동훈, 이홍인
경북대학교 화학과, Korea
Ruthenium complexes have been widely developed to be applied for pharmaceuticals, precursors in a variety of inorganic syntheses, oxo-transfer catalysts, photoinduced energy, water oxidation, and others. Especially, recent advances in pharmaceutical applications of Ru(III) complexes as anticancer drugs have brought much attention to new developments of Ru(III) compounds. Among those, octahedral Ru(III) complexes with chloride and heterocyclic azole ligands have shown promising results. For the clinical success of the complexes, understanding the reactivities of the biomolecule-bound Ru(III) complexes is necessitated. In this study, we have developed a new Ru(III) model complex, [Ru(III)(Tpea)Cl2](ClO4), where Tpea = tris(2-(1-pyrazolyl)ethyl)amine, as a model for the biomolecule-bound Ru(III) complexes. The crystallographic analysis of the complex revealed near perfect octahedral geometry with four N-donor atoms. In-depth study on the catalytic activity of the complex with ABTS [2,2'-azinobis(3-ethylbenzthiazoline-6-sulfonate)]as a co-substrate now reveals the complex has a peroxidase-like reactivity.

상단으로