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  • 09월 12일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제110회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Porous iron-benzenetrycarboxylate (MIL-100-Fe) loaded with Cu+ species: A new adsorbent for thiophenes in liquid fuel

등록일
2012년 8월 28일 14시 44분 04초
접수번호
0409
발표코드
IND.P-124 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
10월 17일 (수요일) 16:00~19:00
발표형식
포스터
발표분야
공업화학
저자 및
공동저자
Nazmul Abedin Khan, 정성화
경북대학교 화학과, Korea
Removal of sulfur-containing compounds from fuels like diesel and gasoline to a low level before utilization has become a great challenge [1]. MIL-100-Fe, one of the typical metal-organic frameworks [2, 3], has been used for the first time as support materials for Cu+ species, which were obtained from one-step synthesis of Cu2O particles at low temperature. The Cu+-loaded MOFs were evaluated as efficient adsorbents for the liquid-phase adsorption of benzothiophene (BT) [4]. The effect of Cu+ loading on the adsorption kinetics and maximum adsorption capacity (Q0) for the adsorption of BT was also studied. The maximum adsorption capacity (Q0) increased with increasing copper loading up to a Cu/Fe (wt./wt.) ratio of 0.07 in Cu+-loaded-MIL-100-Fe, resulting in an increase in the Q0 by 14% compared with the virgin MIL-100-Fe without Cu+ ions. Since the surface area and pore volume decrease with the loading of copper, the increased Q0 over the Cu+-loaded MIL-100-Fe adsorbents suggests specific favorable interactions (probably by π-complexation) between Cu+ and BT. Acknowledgement This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (grant number 2012004528). References [1] V.C. Srivastava, RSC. Adv. 2 (2012) 759. [2] G. F?rey, Chem. Soc. Rev. 37 (2008)191. [3] P. Horcajada, S. Surbl?, C. Serre, D.-Y. Hong,Y. -K. Seo, J.-S. Chang, J. -M. Gren?che, I. Margiolakid, G. F?rey, Chem. Commun. 27 (2007) 2820. [4] N.A. Khan, S.H. Jhung, J. Hazard. Mater. (2012) in press; DOI: 10.1016/j.jhazmat.2012.08.025.

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