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  • 02월 26일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제115회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Porous amino acid-layered double hydroxides and their CO2 uptake behaviors [우수포스터상]

2015년 2월 26일 16시 40분 16초
MAT.P-1186 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
4월 15일 (수요일) 16:00~19:00
저자 및
최고은, 양재훈, 최진호*
이화여자대학교 화학.나노과학과, Korea
A soft chemical route to amino acid layered double hydroxide (LDH) nanohybrids was demonstrated on the basis of an intercalative ion-exchange reaction. Two different amino acids, phenylalanine and glutamic acid, were intercalated and stabilized in the interlayer space of a 2-dimensional double hydroxide lattice by electrostatic interaction. An attempt was also made to understand the effect of the intracrystalline structure of the amino acid in the LDH on the specific surface area, porosity, and gas sorption properties of the hybrid. According to the X-ray diffraction analysis, the basal spacings of LDH intercalated with phenylalanine and LDH intercalated with glutamic acid were expanded to 1.80 and 1.22 nm, respectively, relative to that of the pristine Mg2Al-NO3-LDH (0.88 nm), which indicates that amino acid molecules were successfully intercalated into the LDH. Fourier transform infrared spectra for both samples confirmed that the carboxylic acid group in the amino acid is anionic carboxylate under basic conditions and it eventually interacts with the positively charged LDH surface. From N2 adsorption/desorption analysis, the BET specific surface area of the LDH intercalated with phenylalanine was found to be twice as large as that for the LDH intercalated with glutamic acid. However, the CO2 adsorption capacity of the former was determined to be three times more enhanced than that of the latter, due to an enhanced specific surface area and effective amine sites to form carbamates.