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  • 09월 08일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제116회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Rational Design and Synthesis of Functionalized Ruthenium(II) Organometallics

등록일
2015년 8월 27일 16시 12분 53초
접수번호
0980
발표코드
ORGN.P-383 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
10월 15일 (목요일) 11:00~12:30
발표형식
포스터
발표분야
유기화학
저자 및
공동저자
PALANIELUMALAI, 김동환1, 지기환1,*
울산대학교 화학과, India
1울산대학교 화학과, Korea

Over past few decades the design and synthesis of ruthenacycles got high attention due to their potential in photofunctional materials such as photocatalysts, dye-sensitized solar cells, electroluminescent devices, and sensors. In particular the organometallic based metallacycles are promising candidates for the above mentioned applications. Nevertheless, the biological applications such as cytotoxicity, cellular uptakes, bioimaging studies and anti-tumor properties of the cylometallated organometallic complexes are scare. It is well documented that photophysical properties of metal based supramolecular self-assemblies can be altered by tuning the properties of coordinated ligands. Perpetuation of the research on metal based supramolecular self-assemblies of N-donor ligands, we introduce new flexible di-topic benzimidazolyl core containing ligands, the resent reports are revealed that introducing functionalized benzimidazolyle units in flexible ligand alter the photophysical and antitumor properties of the metallacycles. Herein, we present functionalized phenyl-benzimidazolyl based ditopic ligands and their corresponding ruthenacycles. The ligands and cyclometallated organometallic compounds were characterized by analytical and spectroscopic methods will be presented.


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