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  • 09월 08일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제116회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Porphyrin Boxes: Rationally Designed Porous Organic Cages

2015년 8월 27일 16시 44분 12초
KCS.O-9 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
목 10시 : 30분
Oral Presentation for Young International Chemists
저자 및
ROHMAN MOHAMMAD RUMUM, 홍순상1, 고영호2, 김용휘2, 이은성1, 김기문1,*
기초과학연구원 복잡계 자기조립 연구단, Korea
1포항공과대학교(POSTECH) 화학과, Korea
2기초과학연구원 복잡계자기조립연구단, Korea
Porous organic cages have attracted considerable attention in recent years owing to their potential applications including gas storage and separation. Because high structural and chemical stability and easy processability is essential for many practical applications, the quest for porous organic cages with high thermal and chemical stability has been a subject of intense research. However, to date, most of the porous organic cages have been synthesized with limited synthetic approaches, mainly based on the combination of 2-connected linear (or bent) and 3-connected triangular shaped building units. Here, we present the rational design and synthesis of large porphyrin boxes with permanent porosity and high chemical stability using well-defined and rigid 3-connected triangular and 4-connected square shaped building units. In addition, the size of cavities and windows of the organic cages can be modulated using different sized building units while maintaining the topology of the cage structures. Details of this work will be presented.