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  • 08월 30일 20시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

Self-assembly of Coordination Polymers from Silver(I) salts, AgX (X = ClO4-, PF6-, SbF6-) with a Novel Linking Schiff-base type ligand (L) (L = 1,2-bis((thiophen-3-yl)methylene)hydrazine)

등록일
2006년 8월 7일 11시 42분 34초
접수번호
0064
발표코드
25P65포 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
목 <발표Ⅰ>
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
김성훈, 이순원
성균관대학교 화학과,
A novel linking ligand, L was prepared from hydrazine and 3-thiophen carboxaldehyde by Schiff-base condensation reaction. Ligand L was reacted with several silver salts such as AgClO4, AgPF6, AgSbF6. A self-assembly of AgX and ligand L gave to [Ag(L)2]•(X) (X = ClO4- (1), PF6- (2), SbF6- (3)). As a result, it was found that anions from silver(I) salts play a important role in the construction of coordination polymers. All polymers have Ag•••S and S•••S weak coordination bonds and link by Ag•••O weak interactions in 1 and Ag•••F, F•••S in 2 and C–H•••F in 3. All polymers were structurally characterized by X-ray diffraction.

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