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  • 08월 30일 20시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

COPPER (II) COMPLEXES OF (R,R)-DIAMINOCYCLOHEXANE AND ITS DERIVATIVES WERE USED AS HOMOGENEOUS CATALYSTS FOR ASYMMETRIC HENRY REACTION

등록일
2006년 8월 14일 21시 32분 47초
접수번호
0537
발표코드
25P48포 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
금 <발표Ⅱ>
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
Nguyen Quang Trung, 정종화
경북대학교 화학과,
(R,R)-diaminocyclohaxane was resolved by an economic method and its complex with Copper (II) was formed. The complex structure was determined by X-ray diffraction. Synthesis of derivatives of (R,R)-diaminocyclohaxane with different substituents was resulted in chiral diimines and diamines possessing C2 symmetry. Copper (II) complexes of these chiral ligands were evaluated as homogeneous catalysts for the asymmetric Henry reaction between benzaldehyde and nitromethane leading to high yields and moderate selectivities.

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