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  • 02월 19일 10시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

대한화학회 제121회 학술발표회 및 총회 Phenylimidazole-based homoleptic iridium(III) complexes and their excellent performance in blue phosphorescent organic light-emitting diodes

2018년 2월 6일 18시 28분 25초
INOR.P-96 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
4월 19일 (목요일) 11:00~12:30
Inorganic Chemistry
저자 및
YoungJae Kwon, Chan Hee Ryu, Moon bae Kim, Kang Mun Lee*
Department of Chemistry, Kangwon National University, Korea
We present the preparation of two functionalized phenylimidazole-based facial-homoleptic iridium complexes, FIr (fac-tris(1-(2,6-diisopropylphenyl)-2-(4-fluorophenyl)-1H-imidazolyl)iridium(III)) and CNIr (fac-tris(1-(2,6-diisopropylphenyl)-2-(3-cyanophenyl)-1H-imidazolyl)iridium(III)), and their full characterisation by multinuclear NMR spectroscopy and elemental analysis. Investigation of the molecular structures of the two iridium complexes by single-crystal X-ray diffraction revealed the facial-isomerism. Both complexes showed a definite blue-emission band (λem = 454 nm for FIr and 462 nm for CNIr) in solution and film states at ambient temperature. Moreover, the complexes exhibited significantly high phosphorescent quantum efficiencies in mCP (1,3-bis(N-carbazolyl)benzene) film doped with 5 wt% system (0.87 for FIr and 0.99 for CNIr). Thermogravimetric analysis of the complexes displayed their high thermal stabilities as Td5 values (5 wt% loss) above 390 °C. The frontier energy levels of both complexes calculated from the oxidation and reduction potential were measured to be from approximately −6.1 eV (HOMO) to approximately −2.8 eV (LUMO), which indicated their suitability as novel phosphorescent emitters for blue OLEDs. In addition, multi-layer phosphorescent organic light-emitting diodes using FIr and CNIr as emitters and mCP as a host have been fabricated. The devices exhibited low turn-on voltages and high external quantum efficiencies (18.9% for FIr and 22.5% for CNIr) with blue phosphorescent emission under CIEy = 0.3 (y coordinate of Commission Internationale de l’Eclairage). Moreover, the CNIr based device showed stable lifetimes greater than 550 h at 200 cd•m−2, which is much longer than that of the common phenylpyridine-type blue triplet emitter based device.