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  • 02월 19일 10시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

대한화학회 제121회 학술발표회 및 총회 Difluoro(imidazolium)sulfuranes

등록일
2018년 2월 6일 22시 28분 32초
접수번호
4498
발표코드
INOR.P-105 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
4월 19일 (목요일) 11:00~12:30
발표형식
포스터
발표분야
Inorganic Chemistry
저자 및
공동저자
Soobin Lim, Eunsung Lee*
Department of Chemistry, Pohang University of Science and Technology, Korea
Hypervalent iodine compounds, which enable to transfer electrophilic groups such as trifluoromethyl, aryl, amine, halogen and other groups to substrates have been studied in abundance.1 However, synthesis and reactivity of imidazolium sulfuranes containing hypervalent sulfur with bromine, chloride or cyanide group was reported recently by the Alcarazo group.2 The cyanide group was further transferred to other molecules by C-H bond activation. With the importance of hypervalent sulfurane, we have been exploring imidazolium difluorosulfuranes containing hypervalent sulfur with fluorine. By oxidation of N-heterocyclic carbene (NHC) thioureas with xenon difluoride, we successfully synthesized the imidazolium diflurosulfuranes and it is the first example of stabilization of highly reactive sulfur difluoride. It was characterized by NMR spectroscopy and X-ray crystallography. Their fluorine atom transfer reactivity includes fluorination of carboxylic acid to afford corresponding carbonyl fluoride. Although it was found that fluorination capability of the difluoro(imidazolium)sulfuranes is very limited unlike other deoxyfluorinating sulfur-based reagents, synthetic methods and structural characterization of NHC-SF2 will be added to another important example of carbenes’ unique reactivity. Furthermore, synthesis of thiourea dimers by trimethylsilyl trifluoromethanesulfonate will be presented. Reference (1) Merritt, E.; Olofsson, B. Angew. Chem., Int. Ed. 2009, 48, 9052−9070. (2) Talavera, G.; Peña, J.; Alcarazo, M. J. Am. Chem. Soc. 2015, 137, 8704−8707.

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