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학술발표회초록보기

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  • 02월 19일 10시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제121회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Self-assembly of 1-D azamacrocyclic compound with significant CO2 capture

등록일
2018년 2월 7일 13시 35분 24초
접수번호
4913
발표코드
INOR.P-147 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
4월 19일 (목요일) 11:00~12:30
발표형식
포스터
발표분야
Inorganic Chemistry
저자 및
공동저자
Jong Won Shin*, Dae-Woong Kim1, Dohyun Moon1,*
Division of Daegu, Korea Institute of Science and Technology Informat, Korea
1Beam Operation Team, Pohang Accelerator Laboratory, Korea
Supramolecular compounds constructed from nickel(II) azamacrocyclic compound have been attracted much interest in the development of new functional materials owing to their potential applications in molecular sensing, adsorbents for carbon dioxide and metalloenzymes. To obtain stable 1-D nickel(II) azamacrocyclic compound, we prepared self-assembly of nickel(II) azamacrocyclic complex, containing butyl pendant groups, with 2,7-naphthalenedicarboxylic acid (2,7-NDC) as organic linker. The 2,7-naphthalenedicarboxylic acid (2,7-NDC) can easily bind or interact with transition metal ions as various coordination modes because 2,7-NDC can be fully or partially deprotonated and act as supramolecular interaction donors or acceptors as hydrogen bonding and π-π interaction. Here, we will present the detailed preparation of the [Ni(C16H38N6)(2,7-NDC)] compound, interestion crystal structures as well as gas adsorption.

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