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  • 02월 19일 10시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

대한화학회 제121회 학술발표회 및 총회 The Aerobic Oxidation of Cyclohexene with Copper Silicate, SGU-29

등록일
2018년 2월 7일 15시 40분 32초
접수번호
5343
발표코드
INOR.P-174 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
4월 19일 (목요일) 11:00~12:30
발표형식
포스터
발표분야
Inorganic Chemistry
저자 및
공동저자
Dong Hyeon Lee, Hyun Sung KIM1,*
Department of chemistry, Pukyong National University, Korea
1Department of Chemistry, Pukyong National University, Korea
Catalytic partial oxidation of allylic compound is one of the important routes in industrial chemistry. Nanoporous materials related to zeolites and zeotypes are widely employed as its heterogeneous catalysts or host materials of catalytic molecules in the field of partial oxidation research. Herein, we report the catalytic activity of SGU-29, which is a kind of zeoypes, containing square plane-oxygenated Cu (II) active site for aerobic oxidation of cyclohexene. A catalytic performance was achieved under The SGU-29 heterogeneous catalytic reaction performed under mild reaction conditions, 1 bar of O2 at 70℃. Under the reaction conditions investigated, the aerobic oxidation of cyclohexene mainly produced 2-cyclohexen-1-ol, 2-cyclohexen-1-one, cyclohexenyl hydroperoxide. And conversion efficiency of SGU-29 for cyclohexene oxidation reach 13% under 1 bar of O2 at 70℃ within 4h.
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