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제123회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Facile fabrication of silver nanoparticle arrays by optical-induced melting and dewetting of silver paste

2019년 1월 15일 11시 18분 03초
PHYS.P-79 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
4월 19일 (금요일) 11:00~12:30
Physical Chemistry
저자 및
Joon Ki Kim, Tae-Hyeon Park, Dong-Won Jeong, Zee Hwan Kim, Du-Jeon Jang*
Department of Chemistry, Seoul National University, Korea
Highly dense plasmonic silver nanoparticle (NP) arrays have been fabricated by laser-induced dewetting of commercially available silver paste as a starting bulk material. Laser-irradiation criteria for the laser melting, dewetting, and ablation of silver paste films have been determined in order to understand the optimal conditions of laser fabrication. The first laser-scan mode has produced unprecedented intermediate structures, so called laser-induced fine silver nanostructures (LIFSNs) while the second laser-scan mode has transformed LIFSNs into plasmonic silver NP arrays via the dewetting of the priorly formed nanostructures. The laser-induced fabrication of silver NP arrays has been found to be very sensitive to distance from secondly irradiated laser pulses, suggesting that the fine control of laser intensity is very important. Silver NP arrays of sub-100 nm diameters with narrow size distribution have been fabricated well at a laser scanning rate of ≥50 μm/s. As-prepared silver NP arrays have generated numerous hot spots to show highly strong surface-enhanced Raman scattering signals; the Raman enhancement factor of silver NP arrays for rhodamine 6G has been found as 1.2x106. Overall, our fabrication method of plasmonic silver NP arrays via laser-induced dewetting is facile, scalable, and reproducible.