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제124회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Branching Ratio of 1-Bromo-3-chlorobenzene Cation

등록일
2019년 8월 15일 14시 01분 39초
접수번호
0242
발표코드
PHYS.P-134 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
10월 17일 (목요일) 11:00~12:30
발표형식
포스터
발표분야
Physical Chemistry
저자 및
공동저자
BongGyu Jeong, HyunWook Choi, Jae Kyu Song*, Seung Min Park*
Department of Chemistry, Kyung Hee University, Korea
The rate constant in chemical reactions provided important information. The reaction rate constant predicts how fast the reaction would take place and could be further applied to the dissociation of the substance of interest. In this reason, measurement of rate constant is highly critical. In our lab, experiments relevant to ternary cluster rate constant have been performed. However, the data of experiments and Phase Space Theory (PST) did not match well. To overcome such problem, we will employ Rice-Ramsperger-Kassel-Marcus (RRKM) theory which is easy to access to interpret the experimental results thoroughly. Experiment of 1-Bromo-3-chlorobenzene Cation (3-BrClBz) will be also carried out to verify if molecules also follow the same tendency. Benzene is one of most useful solvents in chemical reactions. In addition, the halogen group is a well-known functional group. Using Time of Flight (TOF) mass spectroscopy we will investigate the internal energy dependence of branching ratio with Modified RRKM theory. The Branching ratio of 3-BrClBz will be obtained at different internal energies (4.37, 4.55, 4.78 eV). The results of the experiments and Modified RRKM calculations are expected to match well.

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