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대한화학회 제124회 학술발표회 및 총회 Ammonia Adsorption in a Hydrogen-Bonded Organic Framework with S-shaped Isotherm

등록일
2019년 8월 20일 17시 11분 34초
접수번호
0553
발표코드
INOR.O-5 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
목 09시 : 40분
발표형식
구두발표
발표분야
Inorganic Chemistry - Oral Presentation of Young Inorganic Chemistry
저자 및
공동저자
Dong Won Kang, Minjung Kang, Hyojin Kim, Jong Hyeak Choe, Daewon Kim, Chang Seop Hong*
Department of Chemistry, Korea University, Korea
Although ammonia is a very useful chemical ingredient for fertilizer and pharmaceutical product, recent researches have suggested it as one of sources of secondary fine dust in rural areas and the amount of gas should be reduced to protect human’s health. To effectively diminish the gas, several porous materials have been investigated, but most porous materials have low working capacity with type I isotherm due to high adsorption enthalpy. In contrast, an adsorbent with S-shaped gas isotherm can exhibit high working capacity in pressure-swing adsorption process. On the best of our knowledge, the adsorbent has been not explored. Herein, we synthesize and analyze a new hydrogen-bonded organic framework that can adsorb NH3 uniquely in an S-shape fashion. The framework can be easily regenerated at room temperature with recyclability in pressure-swing adsorption protocol. Detailed experimental data and explanations will be given in the presentation.
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