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  • 09월 10일 16시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제124회 대한화학회 학술발표회, 총회 및 기기전시회 안내 Effect of Different Solvents on the Properties of Copper Nanoparticles Produced Via Pulsed Laser Ablation and its Enhanced Catalytic Activity

등록일
2019년 8월 29일 16시 45분 52초
접수번호
1878
발표코드
PHYS.P-220 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
10월 17일 (목요일) 11:00~12:30
발표형식
포스터
발표분야
Physical Chemistry
저자 및
공동저자
Talshyn Begildayeva, Seung Jun Lee1, Shreyanka Shankar Naik, Myong Yong Choi1,*
Chemistry, Gyeongsang National University, Korea
1Department of Chemistry, Gyeongsang National University, Korea
Copper nanoparticles with a range of different surface morphologies were synthesized by pulsed laser ablation method using a copper plate as a target in liquid media (deionized water, methanol, ethanol, 1-propanol, butanol, ethylene glycol, hexane and acetonitrile). Moreover, powder X-ray diffraction (XRD) analysis revealed that the species differ not only in shape, but also in composition. When laser ablation of a solid copper plate was carried out in acetonitrile, a core-shell nanostructure of copper@graphitic carbon (Cu@GC) and copper (I) cyanide particles were formed. While spherical and rod-like structured particles of copper (I) and (II) oxide was obtained in deionized water and methanol, respectively. The catalytic activities of the synthesized copper nanoparticles were evaluated for the reduction of 4-nitrophenol to 4-aminophenol, and nitrobenzene to aniline, as a model reaction. Based on the obtained results and pseudo-first order kinetics, the synthesized nanoparticles of copper (II) oxide and copper encapsulated in graphitic carbon layers demonstrated an enhanced catalytic performance towards the reduction of 4-nitrophenol and nitrobenzene. The enhanced catalytic activities of this catalysts might be due the unique surface morphologies and positive synergistic effect between copper nanostructures and graphitic carbon layer. The present investigation was revealed that the pulsed laser ablation of copper plate in various liquid medium is a facile method for producing of copper and copper-based nanoparticles with unique surface structure, compositions and act as an excellent catalytic material.

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