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  • 05월 20일 18시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제125회 대한화학회 학술발표회 및 총회 Coordination of Jacobsen catalyst with N-doped graphene electrocatalytic active species for oxygen reduction reaction

등록일
2020년 2월 6일 10시 29분 55초
접수번호
0684
발표코드
MAT.P-785 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
온라인 PDF 제출
발표형식
포스터
발표분야
Material Chemistry
저자 및
공동저자
Dawoon Jang, Sungjin Park*, Yunseok Shin, Sunghee Park
Department of Chemistry, Inha University, Korea
The catalytic properties of organometallic active species depend on the interaction between the metal center and surrounding ligands. Hybridization of the molecular active species with nanoscale materials can serve as a promising route for creating new catalytic nature. Jacobsen catalysts are well known for converting epoxides to diols by epoxide ring-opening reactions. Herein, an organometallic complex containing a Co atom and a tetra-dentate salen ligand, as a representative Jacobsen catalyst, is hybridized with N-doped graphene-based materials. The coordination structure around the Co center is revealed by X-ray absorption, solid-state nuclear magnetic resonance, and X-ray photoelectron spectroscopic measurements. The resulting hybrid shows excellent catalytic performances for electrochemical oxygen reduction reactions (ORR), such as onset (0.91 V) and half-wave (0.80 V) potentials, current density (5.38 mA/cm2), and turnover frequency (0.2 s-1). Characterizations and electrochemical measurements with control samples suggest that the Co-O2/N2-Ngraphene structure is critical for the catalytic properties. Further study with after-cycle-samples highlighted the superior durability and stability of the active species. Theoretical calculation suggests favored ORR reactions of the fifth axial coordination of Co-O2/N2 by pyridinic N dopants.

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