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제125회 대한화학회 학술발표회 및 총회 Post-synthetic modification of metal-organic materials via the conversion of phenyl C-H bonds

등록일
2020년 2월 6일 13시 55분 13초
접수번호
0851
발표코드
INOR3-1 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
화 14시 : 40분
발표형식
심포지엄
발표분야
Inorganic Chemistry - Recent Trends in Coordination Chemistry
저자 및
공동저자
Jinhee Park
Department of Emerging Materials Science, Daegu Gyeongbuk Institute of Science & Technology, Korea
Post-synthetic modification (PSM) of metal-organic materials (MOMs) such as metal-organic frameworks (MOFs) and metal-organic polyhedra (MOPs) allows the introduction of the desired functionalities while maintaining their framework structures. However, the majority of organic reactions applied in PSM requires additional reactive dangling groups. Thus, the structural complexity after PSM renders structure analyses more difficult. Herein, the post-synthetic conversion of phenyl C-H bonds into C-C bonds via electrophilic aromatic substitutions in MOMs is proposed. Due to the higher electron density of C compared to that of H, crystallographic visualization of this process was possible. The resulting properties of the MOMs after the PSM will be discussed.

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