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  • 09월 23일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

제126회 대한화학회 학술발표회 및 총회 Chemical Fuel-Driven Transient Crystallization

등록일
2020년 9월 7일 17시 42분 46초
접수번호
0876
발표코드
KCS4-8 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
수 16시 : 00분
발표형식
심포지엄
발표분야
KCS - [IBS Symposium] Frontiers in Molecular Recognition and Self-assembly
저자 및
공동저자
Rahul Dev Mukhopadhyay
Center for Self-assembly and Complexity (CSC), Institute for Basic Science, Korea
Fuel-driven self-assembling systems are ubiquitous in nature. Among these, a widely cited example is the formation-deformation mechanism of microtubules via the self-assembly of tubulin proteins fueled by guanosine-5’-triphosphate (GTP). In case of artificially designed fuel-driven, transient self-assembling systems, they often suffer from the accumulation of chemical wastes that interfere with the formation of pristine self-assembled products in subsequent refueled cycles. Recently we discovered that the chemical fuel-driven transient crystallization of a cucurbit[8]uril-based host-guest complex, can be efficiently carried out avoiding the large accumulation of chemical wastes in solution. Here we made use of trichloroacetic acid as a fuel, which undergoes base-catalyzed thermal decarboxylation producing volatile chemical wastes that are spontaneously removed from the solution.1 As a result of such a self-clearance process, the minimal presence of chemical wastes does not significantly influence the formation, morphology and structural integrity of the crystals. Details of our research in this area will be presented.

References 1. Choi, S.; Mukhopadhyay, R. D.; Kim, Y.; Hwang, I. -C.; Hwang, W.; Ghosh, S. K.; Baek, K.; Kim, K. Angew. Chem. Int. Ed. 2019, 58, 16850-16853.

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