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  • 03월 07일 12시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

Amphiphilic Polystyene-Supported IBX Amide: Oxidation of Alcohols in Water

등록일
2007년 2월 13일 11시 40분 17초
접수번호
0991
발표코드
29P145포 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
금 <발표Ⅳ>
발표형식
포스터
발표분야
유기화학
저자 및
공동저자
장형석, 이윤식
서울대학교 화학생물공학부,
The oxidation of alcohols to ketones or aldehydes is an important organic reaction that provides useful intermediates for the preparation of other organic compounds. Moreover oxidizing alcohols in water medium is hot issues in organic chemistry. Polymer supported IBX reagents has attracted much attention due to its numerous advantages. Previously, our group reported several polymer supported IBX. We then proved this reagent was a mild and efficient oxidant in various solvent. However these methods still could not oxidize alcohols in water. Therefore, we synthesize amphiphlic polymer supported IBX amide for oxidize alcohols in water medium. As our expectation, we found that water can be easily diffused into support with catalytic amount of acidic additives. Therefore we investigate different solid supports to improve oxidative properties of amphiphlic polymer supported IBX amide.

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