Inquiry on Abstract abstract@kcsnet.or.kr

Inquiry on Payment member@kcsnet.or.kr

현재 가능한 작업은 아래와 같습니다.
  • 03월 02일 17시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

129th General Meeting of Korean Chemical Society & Exposition Ni-catalyzed substitution process of propargyl tertiary acetates

Submission Date :
2 / 28 / 2022 , 16 : 57 : 16
Abstract Number :
Presenting Type:
Poster Presentation
Presenting Area :
Organic Chemistry
Authors :
Seo Yeon Kim, Eun Jin Cho1,*
Chemistry, Chung-Ang University, Korea
1Department of Chemistry, Chung-Ang University, Korea
Assigned Code :
ORGN.P-621 Assigend Code Guideline
Presenting Time :
April 15 (FRI) 11:00~13:00

We have developed a Ni-catalyzed stereospecific substitution process of propargylic tertiary substrates. The ligand choice was critical for the efficiency and selectivity of the process where only bidentate P^N ligand promoted the process for the construction of new C–C bond. The use of leaving group coordinating to Ni-complex was also critical for the reactivity and selectivity of the process.