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Synthesis and X-ray Crystal Structure of Chiral Pd(II) Complex Ligated by (S)-2-[(2,6-diisopropylanilino)methyl]pyrrolidine and oxidative kinetic resolution of (±)-1-Phenylethanol

등록일
2007년 8월 20일 17시 21분 42초
접수번호
1387
발표코드
30P83포 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
금 <발표Ⅳ>
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
Nguyen Quang Trung, 강윤경, 정종화
경북대학교 화학과,
The chiral Pd(II) complex bearing (S)-2-[(2,6-diisopropylanilino) methyl]pyrrolidine (DIPMP) ligand was synthesized and characterized. Its X-ray crystal structure demonstrates that the DIPMP ligand coordinates to the Pd metal in bidentate fashion which give rise to a 5-membered metallaheterocyclic ring. Besides the intrinsic chirality at the pyrrolidinyl 2-position, additional chiralities of only (S) configuration were induced at the non- and pyrrolidinyl nitrogen atoms due to the stereoselective coordination to the Pd metal ion. This chiral complex was used as a chiral inducer for the oxidative kinetic resolution of (±)-1-phenylethyl alcohol.

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