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  • 02월 22일 16시 이후 : 초록수정 불가능, 일정확인 및 검색만 가능

Novel Metallomesogen Systems Based on Coordination Complexes with Imidazol-Containing Ligands

등록일
2008년 2월 13일 21시 57분 41초
접수번호
1204
발표코드
28P155포 이곳을 클릭하시면 발표코드에 대한 설명을 보실 수 있습니다.
발표시간
금 <발표Ⅳ>
발표형식
포스터
발표분야
무기화학
저자 및
공동저자
태지건
연세대학교 화학과,
Metallomesogens are of significant interest due to combining liquid crystallinity, and optical, electric and magnetic properties brought by metal atoms. We have designed and performed syntheses of various mesogenic imidazole derivatives potentially applicable for obtaining liquid crystalline complexes with all transition metals. Another attribute of metallocomplexes with imidazole-ligands is their unique luminescent properties. In the present work coordination compounds with different d- and f-transition metals were prepared and characterized by element analysis, 1H NMR, IR, and UV-Vis spectroscopies. The synthesized novel metallomesogenic structures exhibit thermotropic smectic mesophases according to POM and DSC studies. Correlations of mesogenic properties on structural variations of the obtained compounds were investigated.

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