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| Type |
Poster Presentation |
| Area |
유기화학 |
| Room No. |
포스터발표장 |
| Time |
4월 20일 (목요일) 11:00~12:30 |
| Code |
ORGN.P-202 |
| Subject |
Synthesis of unnatural carotenoids |
| Authors |
유혜빈, 구상호1,*
명지대학교 에너지융합공학과, Korea
1명지대학교 화학과, Korea
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| Abstract |
Unnatural carotenoids containing various Phenyl substituents exhibit an advantage in terms of stability and electronic characteristics, compared with the natural carotenoids. Chain extension of triene-dialdehyde unit using Julia-Kocienski olefination efficiently provided an extended dialdehyde unit. The Julia-Kocienski olefination of the Phenyl-substituted-C5 -BT(benzothiazole)-sulfone with C10 2,7-diphenyl-2,4,6-octatrienedial efficiently produced tetra-Phenyl-substitued-dial. Carotenoid molecular wires can be assembled by the Wittig reaction between tetra-Phenyl-substituted-dial with 4-thiomethylbenzyl phosphonium bromide. |
| E-mail |
qlsl94@hanmail.net |
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119th General Meeting of the KCS