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| Type |
Poster Presentation |
| Area |
고분자화학 |
| Room No. |
포스터발표장 |
| Time |
4월 21일 (금요일) 13:00~14:30 |
| Code |
POLY.P-1 |
| Subject |
Solid phase extraction of nerve agents' degradation product using polymeric anion exchange film on gold plate |
| Authors |
김현석, 이봉수1, 이용한2,*, 최인성1,*
국방과학연구소 제5기술연구본부, Korea
1KAIST 화학과, Korea
2국방과학연구소 5본부 3부, Korea
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| Abstract |
The detection of chemical Warfare Agents (CWA) and the related chemicals is important for CWC compliance monitoring. Nerve agent, a kind of CWAs, is hydrolyzed to alkyl phosphonic acid in water and soil. Conventional identification methods such as GC-MS, LC-MS and NMR for alkylphosphonic acids require several steps of sample preparation. In this study, anion exchange film was prepared by surface-initiated polymerization on gold plates using trimethyl ammonium functionalized methacralate to selectively extract alkylphosphonic acids from aqueous samples and analyzed by FT-IR spectroscopy. The prepared plates were immersed in an aqueous samples for 10 minutes and then washed with deionized water for extraction of alkylphosphonic acids. The washed plates were briefly dried in a stream of nitrogen gas prior to FT-IR analysis. FT-IR was able to successfully analyze concentration samples at ppm levels. |
| E-mail |
finechem@kaist.ac.kr |
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119th General Meeting of the KCS