119th General Meeting of the KCS

Type Poster Presentation
Area 유기화학
Room No. 포스터발표장
Time 4월 20일 (목요일) 11:00~12:30
Code ORGN.P-207
Subject Catalyst for Oxidation of Pyridine to Pyridine N-oxide using Hydrogenperoxide
Authors 이상희*, 김동희, 김세미
군산대학교 화학과, Korea
Abstract

2-Halopyridine N-oxides, especially 2-chloropyridine N-oxide, are important intermediate products for example in the preparation of pyrithiene, especially zinc pyrithione, which are effective as bactericides and fungicides. Because of the electron-withdrawing properties of the halogens, 2-halopyridines can be oxidised with greater difficulty than other pyridine derivatives. Here, effective and reusable nonmetallic catalyst for oxidation of 2-haloptridine to N-oxide using aqueous hydrogen peroxide, will be described.

E-mail leesh@kunsan.ac.kr