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| Type |
Poster Presentation |
| Area |
무기화학 |
| Room No. |
포스터발표장 |
| Time |
4월 21일 (금요일) 13:00~14:30 |
| Code |
INOR.P-64 |
| Subject |
Oxidative addition of dihaloaryl derivatives toward Pd(0) compounds to give mono or dinuclear Pd(II) complexes containing aryl derivatives |
| Authors |
김용주*, 한용성1, 정강연1, 이순원2
강릉원주대학교 화학과, Korea
1강릉원주대학교 생명화학공학과, Korea
2성균관대학교 화학과, Korea
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| Abstract |
Mono or dinuclear Pd(II) halogen complexes containing various aryl derivatives were prepared from oxidative addition of dihaloaryl derivatives to a Pd(0) complex. For example, oxidative additions of various dihaloaryl derivatives to [Pd(CH2=CHPh)(PR3)2], which could be generated in situ from trans-[PdEt2(PR3)2] (PR3 = PMe3, PEt3) and styrene, gave the mono or dinuclear Pd(II) complexes containing haloaryl derivatives depending on the chemical equivalents. Isolated complexes were characterized from spectroscopic and analytical methods. Experimental details will be presented. |
| E-mail |
yjkim@kangnung.ac.kr |
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119th General Meeting of the KCS