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| Type |
Poster Presentation |
| Area |
무기화학 |
| Room No. |
포스터발표장 |
| Time |
4월 21일 (금요일) 13:00~14:30 |
| Code |
INOR.P-68 |
| Subject |
Photophysical and Structural Propreties of Copper Iodide Polymorphic Complexes
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| Authors |
임한수, 권은진, 박현진, 김태호*, 김진은*
경상대학교 화학과, Korea
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| Abstract |
Two copper iodide complexes [Cu4I4L4](1) and [Cu4I4L4](2) of benzyl(methyl)sulfane(L) have been successfully synthesized and structurally characterized by single crystal X-ray diffraction. Complexes 1 and 2 were crystallized in the space group orthorhombic P212121 and tetragonal I-4, respectively. Complexes 1 and 2 show a discrete complex based on cubane Cu4I4 units. Complexes 1 and 2 are polymorphic complexes. They have different structures with the same formula. Complexes 1 and 2 have different packing structure and intermolecular interactions. Luminescence spectra of the complexes 1 and 2 exhibit emission peaks at 530 nm and 546 nm at room temperature, respectively.
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| E-mail |
justhan12@naver.com |
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119th General Meeting of the KCS