119th General Meeting of the KCS

Type Poster Presentation
Area 재료화학
Room No. 포스터발표장
Time 4월 21일 (금요일) 13:00~14:30
Code MAT.P-342
Subject Adsorptive removal of benzotriazole and benzimidazole from water over a Co-based metal azolate framework
Authors SARKER MITHUN, 정성화*
경북대학교 화학과, Korea
Abstract Co-based metal azolate framework, MAF-5(Co) has been used in the water purification for the removal of toxic water pollutant, benzotriazole (BTA) and benzimidazole (BZI) from aqueous solution. The adsorption capacity of the MAF-5(Co) for BTA and BZI was highest than that of commercial activated carbon or other typical adsorbents including metal–organic frameworks (MOFs). Hydrophobic and π-π interactions between the BTA and MAF-5(Co) were suggested as a plausible mechanism. Based on the zeta potential of MAF-5(Co) and effects of pH on the BTA adsorption, electrostatic interactions between the MAF-5(Co) and BTA species might also affect the adsorption of BTA over MAF-5(Co). Moreover, MAF-5(Co) can be recycled for adsorptive removal of BTA by simple ethanol treatment. Therefore, MAF-5(Co) can be suggested as an efficient adsorbent for BTA and BZI removal from water considering the highest adsorption capacity, excellent reusability, and facile synthesis.
E-mail mithunsarker1981@gmail.com