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|
| Type |
Poster Presentation |
| Area |
무기화학 |
| Room No. |
포스터발표장 |
| Time |
4월 21일 (금요일) 13:00~14:30 |
| Code |
INOR.P-72 |
| Subject |
Methane to methanol conversion over faujasite zeolites encapsulated copper-phthalocyanine |
| Authors |
유혜진, 김현성*
부경대학교 화학과, Korea
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| Abstract |
Metal-phtalocyanine (MPc) complex is widely accepted to be oxidation catalysts for aliphatic C-H bonds in alkanes, alcohols, olefins, aromatic C-H bonds. We have synthesized copper-phthalocyanine in the supercages of faujasite zeolites via “ship-in-a-bottle” procedure. Prepared copper-phthalocyanine zeolites composite was shown to be higher oxidative catalytic activity than the authentic homogeneous catalysts under reaction conditions. Herein, methane was partial oxidized to methanol through copper-phthalocyanine zeolite using nitrous oxide as oxidant. We evaluated the effect of zeolite size and Si/Al ratio of its framework on the catalytic performance. |
| E-mail |
yhj936592@gmail.com |
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119th General Meeting of the KCS