119th General Meeting of the KCS

Type Poster Presentation
Area 무기화학
Room No. 포스터발표장
Time 4월 21일 (금요일) 13:00~14:30
Code INOR.P-73
Subject Di-Ruthenium Acceptor having additional binding sites and their Self-assembly
Authors 위은혜, 류지연, 이준승*
전남대학교 화학과, Korea
Abstract In the supramolecular chemistry, there have been considerable efforts to find the complicated huge supramolecules which are easy to control. To date, coordination driven self-assembly has used electron donors and acceptors for the construction of supramolecules. To achieve more complicated system, we designed di-ruthenium electron acceptor unit possessing electron donating pyridine units. These complexes could have a dual role as a donor and a accepter to promote additional complexation. Three different kinds of ligands and corresponding metalloligands were synthesized and characterized fully including X-ray crystallography. Simple self-assembly to rectangles and further complexations with additional metal precursor to construct complicated huge supramolecules will be presented.
E-mail twinweh@naver.com