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|
| Type |
Poster Presentation |
| Area |
무기화학 |
| Room No. |
포스터발표장 |
| Time |
4월 21일 (금요일) 13:00~14:30 |
| Code |
INOR.P-77 |
| Subject |
Superamolecular Arrays of Metallacyclodimeric Zn(II) Complexes: Solvent Recognition
|
| Authors |
이정준, 이다슬, 정옥상*
부산대학교 화학과, Korea
|
| Abstract |
Self-assembly of ZnX2 (X = Cl, Br, and I) with bidentate Ligand (L) as a hemi-circular bidentate ligand containing chromophore moiety yields a systematic 46-membered metallacyclodimeric unit, [ZnX2(L)]2. These basic skeletons constitute, via interdigitated π∙∙∙π interactions in a staggered fashion, a unique ensemble forming both channels and cages. Specifically, the ensemble with channel and cage significantly stabilizes the solvate molecules. The unprecedented supramolecular structures adsorb/desorb small solvent molecules. |
| E-mail |
jj_lee@pusan.ac.kr |
|
119th General Meeting of the KCS