|
|
| Type |
Poster Presentation |
| Area |
무기화학 |
| Room No. |
포스터발표장 |
| Time |
4월 21일 (금요일) 13:00~14:30 |
| Code |
INOR.P-79 |
| Subject |
Solvent-Template Effects on Coordination Polymerization of Cadmium(II) Complexes |
| Authors |
류민주, 정옥상*
부산대학교 화학과, Korea
|
| Abstract |
Self-assembly of cadmium(II) chloride with new bidentate ligand (L) in different solvent system has been achieved. The self-assembly reactions show significant solvent template effects. Each reaction gives rise to form the composition of Cd(II) : L (1 : 2).
The reaction in acetonitrile yields 1D loop chain of [CdCl2L2]∙2CH3CN.
The reaction in MeOH yields 1D loop chain of [CdCl2L2]∙4CH3OH.
The reaction in EtOH yields interpenetrated 2D sheet of [CdCl2L2].
Constructions of each structure are determined by solvents rather than synthetic methodologies. For some structures, exchange of the solvate molecules in the crystalline solids is carried out, and the 1D skeletal structure discriminates dioxane and CH2Cl2 molecules.
|
| E-mail |
ryuminjoo@gmail.com |
|
119th General Meeting of the KCS