119th General Meeting of the KCS

Type Poster Presentation
Area 물리화학
Room No. 포스터발표장
Time 4월 20일 (목요일) 11:00~12:30
Code PHYS.P-58
Subject Molecular structure and dipole moments of 2-fluorophenylacetylene analyzed by microwave spectroscopy
Authors 가수현, 오정진1,*
숙명여자대학교 지구환경연구소, Korea
1숙명여자대학교 화학과, Korea
Abstract The rotational spectra of the parent and eight 13C isotopomers of 2-fluorophenylacetylene have been measured by chirped-pulsed Fourier-transform microwave spectroscopy in the frequency range of 6-17 GHz. The rotational constants for the parent isotopomer were determined by AABS package program. The dipole moments has been obtained by the Stark effect measurement in the voltage range of +-5 kV. The bond lengths and angles are obtained from the least-squares fitting method and compared to the structure from Kraitchman substitution equation. These experimental structure and dipole moments were compared to the ab initio structure.
E-mail shyun@sookmyung.ac.kr