|
Type |
Poster Presentation |
Area |
물리화학 |
Room No. |
포스터발표장 |
Time |
4월 20일 (목요일) 11:00~12:30 |
Code |
PHYS.P-58 |
Subject |
Molecular structure and dipole moments of 2-fluorophenylacetylene analyzed by microwave spectroscopy |
Authors |
가수현, 오정진1,* 숙명여자대학교 지구환경연구소, Korea 1숙명여자대학교 화학과, Korea |
Abstract |
The rotational spectra of the parent and eight 13C isotopomers of 2-fluorophenylacetylene have been measured by chirped-pulsed Fourier-transform microwave spectroscopy in the frequency range of 6-17 GHz. The rotational constants for the parent isotopomer were determined by AABS package program. The dipole moments has been obtained by the Stark effect measurement in the voltage range of +-5 kV. The bond lengths and angles are obtained from the least-squares fitting method and compared to the structure from Kraitchman substitution equation. These experimental structure and dipole moments were compared to the ab initio structure.
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E-mail |
shyun@sookmyung.ac.kr |
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