Thiacalix[4]-bis-crown (L¹) and its basket-type derivative (L²) were employed and their silver(I) complexes with different topologies are reported. Reaction of L¹ (~10 mM) with three equivalents of AgClO₄ in a mixture of chloroform-methanol afforded an exo-coordinated one dimensional coordination polymer [Ag₂(L¹)(ClO₄)₂]_n (1). When the above synthetic procedure was repeated in a lower concentration of L¹ (~1 mM), a discrete endocyclic disilver(I) complex [Ag₂(L¹)](ClO4)₂ (2) was isolated. On the other hand, tetra-toylated thiacalix[4]arene was found to undergo unprecedented intramolecular cyclization to yield the basket-type derivative L². The mechanism of the basket compound L² via the two stage detosyl and interconversion of the aromatic units is proposed. Using L², two silver(I) complexes with different anions (3: ClO₄^- and 4: PF₆^-) have been isolated. The ClO₄^- complex 3, {[Ag₂(L²)(CH₃OH)(ClO₄)₂]^.4CHCl₃}_n, shows an exo-coordination based 2D infinite structure, in which the anion acts as a linker. The corresponding PF₆^- complex 4, {[Ag(L²)(CH₃OH)](PF₆)}_n, exhibits a multichannel type 3D framework, in which the single channels are further linked by exocyclic silver(I) ions.