119th General Meeting of the KCS

Type Poster Presentation
Area 물리화학
Room No. 포스터발표장
Time 4월 20일 (목요일) 11:00~12:30
Code PHYS.P-59
Subject Exploring the Buried Interface: Electronic Sum-frequency Generation (ESFG) Spectroscopy on Polymer/Substrate Boundaries
Authors 황도익, 이종우, 한기림1, 김성근1,*
서울대학교 생물물리 및 화학생물학과, Korea
1서울대학교 화학부, Korea
Abstract One of the most important and interesting photonic technologies emerged recently is a device that utilizes interconversion between an electrical charge and photon, as clearly demonstrated by examples such as light-emitting diodes (LED) and solar cells. Numerous phenomena crucial to the workings of such devices occur at the interface between two layers. However, difficulty in probing the “buried” interface without damaging materials makes it challenging to investigate the interface in situ. ESFG spectroscopy is a 2nd-order nonlinear optical spectroscopy that can probe only the interfacial region intrinsically by its symmetry-forbidden nature, thus enabling the selective analysis of the electronic structures of the interface while causing no sample damage. In this study, we investigated various polymer/substrate interfaces as a model of organic semiconductor devices by ESFG spectroscopy, in order to unravel correlations that exist between interfacial electronic structures and other parameters.
E-mail cosubini@hotmail.co.kr