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| Type |
Poster Presentation |
| Area |
무기화학 |
| Room No. |
포스터발표장 |
| Time |
4월 21일 (금요일) 13:00~14:30 |
| Code |
INOR.P-92 |
| Subject |
N-substituted 2-iminomethylquinoline and 2-iminomethylpyridine coordinated Zinc(II) complexes: Synthesis, structural characterization and application to polymerization of methyl methacrylate |
| Authors |
허정, 이효선1,*
경북대학교 화학과, Korea
1경북대학교 자연과학대학 화학과, Korea
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| Abstract |
We have synthesized and characterized a series of zinc(II) complexes, namely [LnZnCl2] with ligands [Ln] (Ln = LA – LD), where (LA, = N-(quinolin-2-ylmethylene)cyclopentanamine), (LB = N-(quinolin-2-ylmethylene)cyclohexanamine), (LC = N-(pyridin-2-ylmethylene)-2-furanmethanamine), (LD = 2,6-diethyl-N-(pyridin-2-ylmethylene)aniline). X-ray single crystal diffraction revealed that all Zn(II) complexes have distorted tetrahedral geometry around the zinc metal center. The catalytic activity of these complexes towards the polymerization of methyl methacrylate (MMA) in the presence of MMAO were investigated at 60 ℃. Specifically, [LBZnCl2] showed the highest catalytic activity (2.81 g/molZn•h×104) for the polymerisation of methyl methacrylate (MMA) among the others. |
| E-mail |
gjwjdsla1128@naver.com |
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119th General Meeting of the KCS