119th General Meeting of the KCS

Type Poster Presentation
Area 전기화학
Room No. 포스터발표장
Time 4월 21일 (금요일) 13:00~14:30
Code ELEC.P-528
Subject The electrochemical catalytic reaction of PAA-PVI-[Os(4'4-disubtituted 2'2-bipyridines)2Cl]+/2+with glucose dehydrogenase
Authors 전수연, 전원용1, 최영봉, 김혁한*
단국대학교 화학과, Korea
1단국대학교 나노바이오의과학과, Korea
Abstract Screen printed carbon electrodes (SPCEs) with immobilized osmium-based hydrogel redox polymer, glucose dehydrogenase (GDH) and PEGDGE can be used to apply glucose electrochemical detecting. The osmium redox complexes were synthesized by the coordinating pyridine group having different functional group at 4-position with osmium compounds. The synthesized poly-osmium hydrogel complexes are described as poly(acryl amide)-poly(vinyl imidazole)-[Os(4,4'-disubstituted 2,2'-bipyridines)2Cl]+/2+ (PAA-[Os(4,4'-disubstituted 2,2'-bipyridines)2Cl]+/2+) polymers. The different concentrations of glucose were measured by cyclic voltammetry technique using enzyme-immobilized SPCEs. The resulting electrical currents displayed a good linear response with glucose concentrations with GDH. Therefore, this approach allowed the development of a simple, point of care in the medical field, disposable electrochemical biosensor.
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