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| Type |
Poster Presentation |
| Area |
고분자화학 |
| Room No. |
포스터발표장 |
| Time |
4월 21일 (금요일) 13:00~14:30 |
| Code |
POLY.P-44 |
| Subject |
Polymorphic Superstructures of Pyrene-Based Asymmetric Supramolecule [우수포스터상] |
| Authors |
박민욱, 정광운1,*
전북대학교 고분자나노공학과, Korea
1전북대학교 고분자.나노 공학과, Korea
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| Abstract |
In order to grasp the kinetically controlled polymorphic superstructures from asymmetric supramolecules, a pyrene-attached asymmetric supramolecule (abbreviated as Py3M) was newly synthesized. Superstructures of Py3M exhibited the monotropic phase transition between a stable crystalline phase (K1) and a metastable crystalline phase (K2). Py3M formed two synclinically tilted crystalline superstructures: the 6.75 nm and 4.30 nm periodicities of layered structures for K1 and K2 phases, respectively. The stable K1 phase and metastable K2 were predominantly induced by the π-π interactions and hydrogen-bonds. UV-Vis and PL experiments indicated that the photo-physical properties of Py3M were directly related with their molecular packing superstructures. This work was mainly supported by Mid-Career Researcher Program (2016R1A2B2011041), BK21 Plus program, Korea, and BRL (2015042417) of Korea. |
| E-mail |
clownkarin@Naver.com |
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119th General Meeting of the KCS