119th General Meeting of the KCS

Type Symposium
Area Current Trends in Organic Chemistry Ⅲ: Synthetic Methodology and Catalysis
Room No. 302호
Time FRI 15:55-:
Code ORGN3-4
Subject 1,1-Bisborylalkanes: New Types of Organoboron Compounds for the Chemo, and Regioselective Organic Transformations
Authors 조승환
POSTECH 화학과, Korea
Abstract 1,1-Bisorganometallic reagents are valuable starting materials for the construction of multifunctionalized molecules. Among them, 1,1-bisborylalkanes, which contain two boryl groups at the same carbon center, are particularly attractive due to their ease of handling, non-toxicity, stability, and propensity to undergo a variety of organic transformations. In this context, our lab is highly interested in the development of regio, chemo and stereoselective organic reactions using 1,1-bisborylalkanes as new types of 1,1-bisorganometallic reagents. In this symposium, the details about our recent findings using 1,1-bisborylalkanes in a range of organic transformations will be presented including 1) an unprecedented transition-metal-free deborylative alkylation of N-heteroaromatic compounds using 1,1-bisborylalkanes as alkyl sources and 2) an unusual chemoselective coupling of 1,1-bisborylalkanes for the transition-metal-free borylation of aryl and vinyl halides.
E-mail seunghwan@postech.ac.kr