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|
| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Exhibition Hall 2+3 |
| Time |
10월 19일 (목요일) 11:00~12:30 |
| Code |
MAT.P-374 |
| Subject |
On-chip silylation of nerve agents' degradation products for the head space GC-MS analysis using anion exchange polymeric film coated gold substrate |
| Authors |
Hyunsuk Kim, Bong Soo Lee1, Yong Han Lee*, INSUNG CHOI1,*
Agency for Defense Development, Korea
1Department of Chemistry, Korea Advanced Institute of Science and Technology, Korea
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| Abstract |
Identification of alkyl methylphosphonic acids in aqueous samples is important for the monitoring compliance with Chemical Weapons Convention. In order to analyze the alkylmethylphosphonic acids in the complex matrices, it is essential to remove the interfering substance through a sample preparation process. In this study, we propose solid phase extraction of alkyl methylphosphonic acids using gold chips coated with poly(triethylammonium ethyloxymethacrylate) film prepared by surface initiated polymerization and the on-chip silylation of extracted alkyl methylphosphonic acids for Headspace GC-MS analysis. In this study, the proposed analytical method was optimized and verified through a series of experiments. The optimized method was successfully applied to OPCW proficiency test sample. |
| E-mail |
finechem@kaist.ac.kr |
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120th General Meeting of the KCS