120th General Meeting of the KCS

Type Symposium
Area Recent Trends in Organometallic Chemistry
Room No. Room 211+212+213
Time FRI 16:00-:
Code INOR2-5
Subject Luminescent Salen-Based Aluminum and Indium Complexes: Control of Optical Properties by Manipulation of Functional Groups
Authors Myung Hwan Park
Department of Chemistry Education, Chungbuk Natioanl University, Korea
Abstract Various organometallic complexes based on group 13 metals, such as Al and Ga, have been widely reported as prominent optoelectronic materials due to their excellent electronic and photophysical properties. The luminescent properties of these luminophores can be controlled by a systematic modulation of the ligand frameworks. The incorporation of various substituents into the ligand as a scaffold for transition-metal complexes can induce fascinating photophysical properties, such as emission color tuning and quantum efficiency modifications, leading to an expansion of their use as promising luminescent materials. In a continuous effort to explore a novel class of color-tunable luminophores, we investigated salen-based aluminum and indium complexes with various functional groups. In particular, to the best of our knowledge, there have been no reported studies on monomeric indium complexes that display multicolor emission features due to the simple alteration of their substituents. In this presentation, the details of the foregoing chemistry will be presented along with their intriguing optical properties.
E-mail mhpark98@chungbuk.ac.kr