|
|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2+3 |
| Time |
10월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-6 |
| Subject |
Unprecedented Reactivity of Copper(II)-Alkylperoxo Complexes in Aldehyde Deformylation |
| Authors |
bohee kim, Jaeheung Cho*
Emerging Materials Science, Daegu Gyeongbuk Institute of Science & Technology, Korea
|
| Abstract |
Copper(II)-akylperoxo adducts, [Cu(CHDAP)(OOR)]+ (CHDAP = N,N’-dicyclohexyl-2,11-diaza[3,3](2,6)pyridinophane; R = C(CH3)2Ph and tBu), were prepared and characterized by various physicochemical methods such as UV-vis, CSI-MS, resonance Raman and EPR. These are the first synthetic Cu(II)-alkylperoxo complexes that can perform aldehyde deformylation (i.e., nucleophilic reactivity) under the stoichiometric reaction conditions, which was confirmed by kinetic studies. Moreover, the metastable Cu(II)-alkylperoxo complexes are able to catalyze C-H bond activation through O-O bond cleavage at higher temperature.
|
| E-mail |
kbh522@dgist.ac.kr |
|
120th General Meeting of the KCS