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| Type |
Poster Presentation |
| Area |
Material Chemistry |
| Room No. |
Exhibition Hall 2+3 |
| Time |
10월 19일 (목요일) 11:00~12:30 |
| Code |
MAT.P-377 |
| Subject |
Removal of Pharmaceuticals and Personal Care Products from Water by Adsorption with Functionalized Metal-organic Frameworks: Contribution of Hydrogen-bonding |
| Authors |
HyungJun An, Sung Hwa JHUNG*
Department of Chemistry, Kyungpook National University, Korea
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| Abstract |
Some pharmaceuticals and personal care products (PPCPs) (such as naproxen, ibuprofen and oxybenzone) were adsorbed from aqueous solutions on highly porous metal-organic framework (MOF) MIL-101 with and without functionalization. Adsorption results showed that MIL-101s with H-donor functional groups such as –OH and –NH2 were very effective for naproxen adsorption, despite a decrease in porosity, probably because of H-bonding between O atoms on naproxen and H atoms on the adsorbent. For this reason, MIL-101 with two functional groups capable of H-bonding (MIL-101-(OH)2) exhibited remarkable adsorption capacity based on adsorbent surface area. The favorable contributions of –OH and –(OH)2 on MIL-101 in the increased adsorption of ibuprofen and oxybenzone (especially based on porosity) confirmed again the importance of H-bonding mechanism. The adsorbent with the highest adsorption capacity, MIL-101-OH, was very competitive when compared with carbonaceous materials, mesoporous materials, and pristine MIL-101. Moreover, the MIL-101-OH could be recycled several times by simply washing with ethanol, suggesting potential application in the adsorptive purification of water or removal of PPCPs. |
| E-mail |
ahj8228@naver.com |
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120th General Meeting of the KCS