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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2+3 |
| Time |
10월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-14 |
| Subject |
Synthesis and catalytic properties of cis-(R)-(BINAP)bis(azido)palladium(II) |
| Authors |
Yong-Joo Kim*, Sun Myeong Choi1, Soon W. Lee2
Department of Chemistry, Kangnung-Wonju National University, Korea
1Department of Chemistry, Gangneung-Wonju National University, Korea
2Department of Chemistry, Sungkyunkwan University, Korea
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| Abstract |
New Pd(II) azido complex beating (R)-BINAP (2,2’-bis(diphenylphosphino)-1,1’-binaphthyl), which was prepared from reaction of the corsponding (BINAP)PdCl2 with excess NaN3, examined chemical property toward organic isothiocyanate to afford S-coordinated tetrazole-thiolato Pd(II) compounds. Also, the cataltic C-C coupling reacions using cis-(R)-(BINAP)bis(azido)palladium(II)were carried out. |
| E-mail |
yjkim@kangnung.ac.kr |
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120th General Meeting of the KCS