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|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2+3 |
| Time |
10월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-16 |
| Subject |
Cu(I) Coordination Polymer Based on Thioether Ligands with Pyridine Dicarboxylic Anhydride |
| Authors |
Juhyeon Park, Hyunjin Park, Hansu Im, Tae Ho Kim*, Myong Yong Choi*
Department of Chemistry, Gyeongsang National University, Korea
|
| Abstract |
The ligands (L1, L2, L3and L4) with thioether substituents were synthesized by the reaction of pyridine dicarboxylic anhydride and 2-(cyclohexylthio)ethylamine or 2-(tert-butylthio)ethylamine. One Cu(I) coordination polymer (CP) {[Cu4I4L22]·MeCN}n (1) was prepared by the reaction of CuI and L2. CP 1 showed a 1D loop chain structure based on cubane Cu4I4 cluster nodes. CP 1 was crystalized in space group triclinic P-1. Remarkably, CP 1 is non-emissive at room temperature in comparison with most emissive cubane Cu4I4 complexes. The results of our investigation including syntheses, structural characterization, thermal properties of one new Cu(I) coordination polymer is presented. |
| E-mail |
jhpark_@gnu.ac.kr |
|
120th General Meeting of the KCS