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|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2+3 |
| Time |
10월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-24 |
| Subject |
Construction and photoreaction of 1D Zn(II) suprachannels |
| Authors |
Haeri Lee, Ok-Sang Jung*
Department of Chemistry, Pusan National University, Korea
|
| Abstract |
Self-assembly of ZnX2 (X- = Cl-, Br-, and I-) with a bidentate ligand (L) yields 1D zigzag-chains, [ZnX2L]. The 1D chains form an ensemble constituting a unique suprachannels. The main driving forces for suprachannel ensembles are C-H∙∙∙π and π∙∙∙π interactions. Within the voids, solvate molecules exist depending on the anions and solvent system. The exchange of the solvate molecules in a crystalline solid state was carried out. Furthermore, molecular behaviors under UV-irradiation have been investigated. |
| E-mail |
haeril@pusan.ac.kr |
|
120th General Meeting of the KCS