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Type |
Poster Presentation |
Area |
Inorganic Chemistry |
Room No. |
Exhibition Hall 2+3 |
Time |
10월 19일 (목요일) 11:00~12:30 |
Code |
INOR.P-39 |
Subject |
Nanoporous Copper Silicate, SGU-29 for Partial Oxidation of C-H bond |
Authors |
hyejin yu, Hyun Sung KIM* Department of Chemistry, Pukyong National University, Korea |
Abstract |
By using the zeolite-based heterogeneous catalytic system and its selective reactivity, it is possible to design for the desired chemical reaction. Herein, we report the catalytic activity for partial oxidation of cyclohexane of transition metal oxide molecular sieve, SGU-29 containing square plane-oxygenated Cu active site.
We found that cyclohexane was effectively partial oxidized to useful chemical form, cyclohexanol and cyclohexanone through SGU-29 zeolite using tert-butyl hydrogen peroxide as oxidant. Catalyst activity of SGU-29 can be optimized by varying the amount of chemicals and reaction temperature. And oxidation of cyclohexane reach ~20% yield of cyclohexanol and cyclohexanone under optimized conditions. Consequently, microporous of transition metal oxide molecular sieve, SGU-29 as catalyst has been proved as one of the excellent candidate for partial oxidation of carbon-hydrogen bonds.
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E-mail |
yhj936592@gmail.com |
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