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|
| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2+3 |
| Time |
10월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-42 |
| Subject |
The formation of Ruthenium Supramolecules Based on Asymmetric Metalloligands Ligands
|
| Authors |
Eun Hye Wi, Ji Yeon Ryu, Junseong Lee*
Department of Chemistry, Chonnam National University, Korea
|
| Abstract |
In the supramolecular chemistry, symmetric ligands with ruthenium electron are the most extensively exploited building blocks in coordination-based supramolecular assembly. In contrast, the attempts to utilize asymmetric ligands in the assembly are far less common because the asymmetric system can provide more complicated architectures with larger number of possible products. As a new asymmetric metalloligand system, we designed asymmetric di-ruthenium electron acceptor units possessing electron donating pyridine units. These complexes could have a dual role as a donor as well as an accepter in the self-assembly to promote additional complexation. Two kinds of asymmetric ligands and corresponding metalloligands were synthesized and characterized by various methods including X-ray crystallography. Simple self-assembly to rectangles and further complexations with additional metal precursor to construct complicated heterobimetallic complex will be presented. |
| E-mail |
twinweh@naver.com |
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120th General Meeting of the KCS