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| Type |
Poster Presentation |
| Area |
Inorganic Chemistry |
| Room No. |
Exhibition Hall 2+3 |
| Time |
10월 19일 (목요일) 11:00~12:30 |
| Code |
INOR.P-43 |
| Subject |
Heterometallic Supramolecular Cage with Homo- or Heteroleptic Aluminum(Ⅲ) Metalloligands Containing β-diketonate Ligands |
| Authors |
Ji Min Lee, Junseong Lee*
Department of Chemistry, Chonnam National University, Korea
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| Abstract |
Recent researches in supramolecular chemistry have focused on the heterometallic assembly by means of metalloligand electron donors. β-diketonate ligand possessing pyridyl groups is one of useful and convenient ligands for the formation of octahedral metalloligands. To achieve Al heterometallic supramolecules,we designed aluminum(Ⅲ) metalloligands containing β-diketonate ligands and used them in the heterometallic supramolecular assembly. The reaction of (tris-{1-(4-pyridyl)acetylacetonato})Al(Ⅲ)(L1) and diruthenium electron accepters(A1) resulted in the formation of [2+3] heterometallic trigonal bipyramidal cage. and the other aluminum complex (di(4-pyridyl)-1,3-propanedionato)2(acetylacetonato)Al(Ⅲ)(L3) and cis-platinumCl2(PEt3)2 electron acceptor(A2) were reacted to produce [4+8] heterometallic tetragonal cage. |
| E-mail |
hs192536@naver.com |
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120th General Meeting of the KCS